IndiumV3, Main, Repository, bibRecord, 000842

New ternary indide La2Pd3In4

Identifieur interne : 000842 ( Main/Repository ); précédent : 000841; suivant : 000843

New ternary indide La2Pd3In4

Auteurs : RBID : Pascal:13-0350696

Descripteurs français

Pascal (Inist)
- Four arc, Diffraction RX, Palladium, Indium, Réseau hexagonal, Conduction métallique, Structure cristalline, Propriété magnétique, Propriété électrique, Monocristal, Composé intermétallique, 6166, 75.

English descriptors

KwdEn :
- Arc furnaces, Crystal structure, Electrical properties, Hexagonal lattices, Indium, Intermetallic compounds, Magnetic properties, Metallic conduction, Monocrystals, Palladium, XRD.

Abstract

A new indide La₂Pd₃In₄ was prepared by arc-melting of the elements. X-ray diffraction on single crystals yielded: Pnma, oP36, a = 21.8112(6) Å, b = 4.4680(1) Å, c = 8.4145(2) Å, Z = 4, R = 0.0355. La₂Pd₃In₄ is a new site exchange variant of the YNi₅Si₃ type. The main geometrical motif is here a set of condensed, palladium-centered trigonal prisms composed of lanthanum and indium atoms. Palladium and indium atoms form a complex three-dimensional [Pd₃In₄] polyanion. The lanthanum atoms are located in the two types of distorted hexagonal channels. The compound is diamagnetic and exhibits metallic conductivity.

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Pascal:13-0350696

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">New ternary indide La<sub>2</sub>
Pd<sub>3</sub>
In<sub>4</sub>
</title>
<author><name sortKey="Nesterenko, S N" uniqKey="Nesterenko S">S. N. Nesterenko</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Chemistry Department of the Lomonosov Moscow State University, Leninskie Gory 1</s1>
<s2>119991 Moscow</s2>
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<author><name sortKey="Tursina, A I" uniqKey="Tursina A">A. I. Tursina</name>
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<s2>119991 Moscow</s2>
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<author><name sortKey="Noel, H" uniqKey="Noel H">H. Noël</name>
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<author><name sortKey="Seropegin, Y D" uniqKey="Seropegin Y">Y. D. Seropegin</name>
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<country>Pologne</country>
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<term>Intermetallic compounds</term>
<term>Magnetic properties</term>
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<front><div type="abstract" xml:lang="en">A new indide La<sub>2</sub>
Pd<sub>3</sub>
In<sub>4</sub>
 was prepared by arc-melting of the elements. X-ray diffraction on single crystals yielded: Pnma, oP36, a = 21.8112(6) Å, b = 4.4680(1) Å, c = 8.4145(2) Å, Z = 4, R = 0.0355. La<sub>2</sub>
Pd<sub>3</sub>
In<sub>4</sub>
 is a new site exchange variant of the YNi<sub>5</sub>
Si<sub>3</sub>
 type. The main geometrical motif is here a set of condensed, palladium-centered trigonal prisms composed of lanthanum and indium atoms. Palladium and indium atoms form a complex three-dimensional [Pd<sub>3</sub>
In<sub>4</sub>
] polyanion. The lanthanum atoms are located in the two types of distorted hexagonal channels. The compound is diamagnetic and exhibits metallic conductivity.</div>
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In<sub>4</sub>
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<s3>FRA</s3>
<sZ>3 aut.</sZ>
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<fA14 i1="03"><s1>Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410</s1>
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Pd<sub>3</sub>
In<sub>4</sub>
 was prepared by arc-melting of the elements. X-ray diffraction on single crystals yielded: Pnma, oP36, a = 21.8112(6) Å, b = 4.4680(1) Å, c = 8.4145(2) Å, Z = 4, R = 0.0355. La<sub>2</sub>
Pd<sub>3</sub>
In<sub>4</sub>
 is a new site exchange variant of the YNi<sub>5</sub>
Si<sub>3</sub>
 type. The main geometrical motif is here a set of condensed, palladium-centered trigonal prisms composed of lanthanum and indium atoms. Palladium and indium atoms form a complex three-dimensional [Pd<sub>3</sub>
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New ternary indide La2Pd3In4

New ternary indide La2Pd3In4

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

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Pour manipuler ce document sous Unix (Dilib)

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